Advanced Batteries: Materials Science Aspects - download pdf or read online

By Robert Huggins

ISBN-10: 0387764232

ISBN-13: 9780387764238

ISBN-10: 0387764240

ISBN-13: 9780387764245

Storage and conversion are severe parts of vital energy-related applied sciences. Advanced Batteries: fabrics technological know-how Aspects employs fabrics technological know-how strategies and instruments to explain the severe good points that keep watch over the habit of complex electrochemical garage systems.

This quantity specializes in the fundamental phenomena that make sure the houses of the parts, i.e. electrodes and electrolytes, of complex platforms, in addition to experimental equipment used to review their severe parameters. This targeted fabrics technology process makes use of strategies and methodologies various from these general in electrochemical texts, providing a clean, basic and instructional viewpoint of complex battery systems.

Graduate scholars, scientists and engineers drawn to electrochemical strength garage and conversion will locate Advanced Batteries: fabrics technology Aspects a priceless reference.

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2 Simple Chemical and Electrochemical Reactions First consider a simple chemical reaction between two metallic materials A and B, which react to form an electronically conducting product AB. 1) The driving force for this reaction is the difference in the values of the standard Gibbs free energy of the products - AB in this case, and the standard Gibbs free energies of the reactants, A and B. A. 3) Values of this parameter for many materials can be found in a number of sources [1–3]. While the morphology of such a reaction can take a number of forms, consider a simple 1-dimensional case in which the reactants are placed in direct contact and the product phase AB forms between them.

There is a two-phase plateau, a single-phase solid solution region, followed by another two-phase plateau. This interpretation is reinforced by the results of X-ray diffraction experiments shown in Fig. 10 [6]. It is seen that the lattice parameters remain constant within two-phase regions, and vary with the composition within the single-phase solid solution region. 5 The Coulometric Titration Technique The simple examples discussed so far in this chapter assume that the requisite thermodynamic data are already known.

29) However, as shown earlier, if self-discharge results from the leakage of electrons through the electrolyte there must be both electronic and ionic current with equal values. 30) Measurements of the rate of heat generation by Joule heating under open circuit conditions can be used to evaluate the rate of self-discharge in practical cells. 6 What If Current is Drawn from the Cell? If current is drawn from the cell into an external circuit, the normal mode of operation when chemical energy is converted into electrical energy, it flows through the ionic impedance, Zi .

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Advanced Batteries: Materials Science Aspects by Robert Huggins

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